Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN 1)cobalt(II)

نویسندگان

  • Tuncer Hökelek
  • Güner Saka
  • Barış Tercan
  • Füreya Elif Öztürkkan
  • Hacali Necefoğlu
چکیده

In the mononuclear title compound, [Co(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromo-benzoate anion, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule; all ligands are monodentate. The four O atoms in the equatorial plane around Co(II) form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010